One-pot vinylogous aldol addition of beta,gamma-unsaturated esters under mild conditions


Akcok İ. , Cagir A.

NEW JOURNAL OF CHEMISTRY, cilt.39, ss.5121-5123, 2015 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 39 Konu: 7
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1039/c5nj00961h
  • Dergi Adı: NEW JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.5121-5123

Özet

We described a one-pot vinylogous aldol addition of methyl 3-butenoate to aromatic aldehydes in the presence of silver salts and the TMSCl-TBAF mixture. The reaction can be done simply by sequentially mixing reagents in situ, and it does not require any catalyst or dienolate ether preparations prior to the reaction.