Synthesis of L-Cysteine Capped Silver Nanoparticles in Acidic Media at Room Temperature and Detailed Characterization


Panhwar S., Hassan S. S. , Mahar R. B. , Canlier A. , Sirajuddin S., Arain M.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.28, ss.863-870, 2018 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 28 Konu: 3
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1007/s10904-017-0748-9
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Sayfa Sayısı: ss.863-870

Özet

This work reports a simple and one pot synthesis of water dispersible l-cysteine stabilized silver nanoparticles (l-CYS-AgNPs) in an acidic media. Silver nanoparticles were synthesized within few minutes of reaction time (< 5 min) at room temperature without needing to heat and use of any hazardous organic solvents. Prepared nanoparticles were characterized by UV-Visible spectroscopy, Fourier transform infrared spectroscopy, transmission electron microscopy, atomic force microscopy, X-ray diffraction and zeta potential analysis, respectively. Surface plasmon resonance band of AgNPs which was observed at 392 nm by UV-Visible spectroscopy indicated successful formation of l-CYS-AgNPs in acidic media. Imaging techniques showed that AgNPs possess spherical morphology and average size of 25 nm. Nanoparticles were stable for more than 2 months when stored at ambient temperature. This approach is a facile and rapid one pot synthesis which can be stored as a homogenous aqueous dispersion for more than 2 months. Being stabilized by a sulfur-containing amino acid (l-cysteine) and the synthesis carried out in a moderately acidic media (pH 5.3) are distinctive aspect of this work. These stable l-CYS-AgNPs could be used as a catalyst and sensor applications for advanced perspective against water pollution and industrial effluents.