Colloidal Aluminum Antimonide Quantum Dots

Jalali H. B., Sadeghi S., ŞAHİN M., Ozturk H., Ow-Yang C. W., Nizamoglu S.

CHEMISTRY OF MATERIALS, cilt.31, sa.13, ss.4743-4747, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31 Sayı: 13
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1021/acs.chemmater.9b00905
  • Dergi Adı: CHEMISTRY OF MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.4743-4747
  • Abdullah Gül Üniversitesi Adresli: Evet

Özet

AlSb is a less studied member of the III-V semiconductor family, and herein, we report the colloidal synthesis of AlSb quantum dots (QDs) for the first time. Different sizes of colloidal AlSb QDs (5 to 9 nm) were produced by the controlled reaction of AlCl3 and Sb[N(Si(Me)(3))(2)](3) in the presence of superhydride. These colloidal AlSb quantum dots showed excitonic transitions in the UV-A region and a tunable band edge emission (quantum yield of up to 18%) in the blue spectral range. Among all III-V quantum dots, these quantum dots show the brightest core emission in the blue spectral region.