Novel oxorhenium(V) '3+1' mixed ligand complexes with 3-thiapentane-1,5-dithiolate and functional mercaptobenzoyl amino acid ethyl ester


Chowdhury S., Canlier A. , Koshino N., Ikeda Y.

INORGANICA CHIMICA ACTA, vol.361, no.1, pp.145-152, 2008 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 361 Issue: 1
  • Publication Date: 2008
  • Doi Number: 10.1016/j.ica.2007.06.038
  • Title of Journal : INORGANICA CHIMICA ACTA
  • Page Numbers: pp.145-152

Abstract

Oxorhenium(V) complexes with '3+1' mixed ligands, [ReO(SSS)L], where SSS is eta(3)-(SCH2CH2SCH2CH2S), L = eta(1)-(C6H4COOH-4S), eta(1)-(C6H4CONHCH2COOEt-4-S), eta(1)-(C6H4CONHCH(CH3)COOEt-4-S), and eta(1)-(C6H4CONHCH(CH2Ph)COOEt-4-S), have been synthesized. These L ligands and [ReO(SSS)L] complexes were characterized by IR, H-1 NMR, C-13 NMR, and MAS spectrometers. Molecular structure of [ReO(SSS) {eta(1)-(C6H4COOH-4-S)}] complex was determined to be a distorted square pyramidal by single crystal X-ray analytical method. (c) 2007 Elsevier B.V. All rights reserved.