Separation of Mn and Fe from a Manganiferous Iron Ore Using Horse Dung as Reductant: A Zero Waste Approach


TOP S., ALTINER M., KURŞUNOĞLU S.

JOM, cilt.74, sa.2, ss.474-483, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 74 Sayı: 2
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1007/s11837-021-05057-3
  • Dergi Adı: JOM
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, ABI/INFORM, Aerospace Database, Applied Science & Technology Source, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.474-483
  • Abdullah Gül Üniversitesi Adresli: Evet

Özet

The separation of manganese and iron from a manganiferous iron ore using horse dung (biomass) as reductant was investigated in a sulfuric acid solution, and 99.80% Mn and 17.76% Fe were extracted into the solution under these leaching conditions: 1 M sulphuric acid concentration, 120 g/L biomass, 1/10 solid to liquid ratio, 300 rev/min stirring speed, 90 degrees C leaching temperature, and 3 h leaching time. In the first precipitation step, the iron and aluminum were first rejected from the solution at pH 5.04. Thereafter, 98.58% Mn was precipitated at pH 10 in the second step. The precipitate was identified as a pyrochroite mineral. After the leaching, the residue was subjected to a carbothermal reduction process conducted at 700 degrees C for 10 min in the presence of no extra reductant. The residue was converted to magnetite mineral, which can be easily recovered by magnetic separation. Based on the experimental results, a flowsheet has been proposed.